Now showing 1 - 10 of 121
  • 2004Journal Article
    [["dc.bibliographiccitation.firstpage","1177"],["dc.bibliographiccitation.issue","6"],["dc.bibliographiccitation.journal","Organometallics"],["dc.bibliographiccitation.lastpage","1179"],["dc.bibliographiccitation.volume","23"],["dc.contributor.author","Chai, J. F."],["dc.contributor.author","Zhu, H. P."],["dc.contributor.author","Fan, H. J."],["dc.contributor.author","Roesky, H. W."],["dc.contributor.author","Magull, Joerg"],["dc.date.accessioned","2018-11-07T10:50:18Z"],["dc.date.available","2018-11-07T10:50:18Z"],["dc.date.issued","2004"],["dc.description.abstract","The synthesis and X-ray crystal structures of the monomethyl and -phenyl manganese complexes [LMn(mu-Me)](2) (2) and LMnPh (3) (L = HC(CMeNAr)(2), Ar = 2,6-iPr(2)C(6)H(3)) are reported. These complexes represent the first structurally characterized neutral dimeric manganese(II) monoalkyl complexes and monomeric manganese(II) monoaryl complexes. Furthermore, compound 3 shows an interesting coplanar arrangement of the phenyl group and the chelating ligand."],["dc.identifier.doi","10.1021/om030645i"],["dc.identifier.isi","000220093200002"],["dc.identifier.uri","https://resolver.sub.uni-goettingen.de/purl?gro-2/48625"],["dc.notes.status","zu prüfen"],["dc.notes.submitter","Najko"],["dc.publisher","Amer Chemical Soc"],["dc.relation.issn","0276-7333"],["dc.title","Structurally characterized neutral monoalkyl and -aryl complexes of manganese(II)"],["dc.type","journal_article"],["dc.type.internalPublication","yes"],["dc.type.peerReviewed","yes"],["dc.type.status","published"],["dspace.entity.type","Publication"]]
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  • 2012Journal Article
    [["dc.bibliographiccitation.firstpage","6953"],["dc.bibliographiccitation.issue","35"],["dc.bibliographiccitation.journal","European Journal of Organic Chemistry"],["dc.bibliographiccitation.lastpage","6958"],["dc.contributor.author","de Meijere, Armin"],["dc.contributor.author","Redlich, Stefan"],["dc.contributor.author","Kozhushkov, Sergei I."],["dc.contributor.author","Yufit, Dmitry S."],["dc.contributor.author","Magull, Joerg"],["dc.contributor.author","Vidovic, Denis"],["dc.contributor.author","Schill, Heiko"],["dc.contributor.author","Menzel, Henning"],["dc.date.accessioned","2018-11-07T09:02:47Z"],["dc.date.available","2018-11-07T09:02:47Z"],["dc.date.issued","2012"],["dc.description.abstract","(E,E)-1,2,3,4-Tetracyclopropylbuta-1,3-diene (3) and (Z,Z)-1,4-diodo-1,2,3,4-tetracyclopropylbuta-1,3-diene (4) were prepared from dicyclopropylacetylene via an intermediate 2,3,4,5-tetracyclopropyltitanacyclopentadiene (2) in 91 and 77% yield, respectively. In the crystal, 3 adopts a conformation with an almost coplanar (phi = 163 degrees) 1,3-diene core, with the inner vinylcyclopropane units in an orthogonal and the outer vinylcyclopropane moieties in an s-trans orientation. This diene, like 2,3-cyclopropylbuta-1,3-diene (5), undergoes facile concerted [4+2] cycloadditions at 130 degrees C with dimethyl acetylenedicarboxylate as well as N-phenylmaleimide and at 0 degrees C with N-phenyltriazolinedione. An X-ray crystal structure analysis of 2,3-dicyclopropylbuta-1,3-diene (5) also reveals a coplanar inner core with the vinylcyclopropane units in essentially orthogonal (phi(av)=89.3 degrees) orientation. Differential scanning calorimetry (DSC) measurements indicate that 3 undergoes significant internal reorganization on going from the liquid to the crystalline phase, and a gauche conformer of 3 may well be favored over the s-trans conformer in the liquid."],["dc.identifier.doi","10.1002/ejoc.201201054"],["dc.identifier.isi","000312035900015"],["dc.identifier.uri","https://resolver.sub.uni-goettingen.de/purl?gro-2/24762"],["dc.notes.status","zu prüfen"],["dc.notes.submitter","Najko"],["dc.publisher","Wiley-v C H Verlag Gmbh"],["dc.relation.issn","1434-193X"],["dc.title","(E,E)-1,2,3,4-Tetracyclopropylbuta-1,3-diene: Synthesis and Some of Its Properties"],["dc.type","journal_article"],["dc.type.internalPublication","yes"],["dc.type.peerReviewed","yes"],["dc.type.status","published"],["dspace.entity.type","Publication"]]
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  • 2005Journal Article
    [["dc.bibliographiccitation.firstpage","281"],["dc.bibliographiccitation.issue","2"],["dc.bibliographiccitation.journal","Angewandte Chemie International Edition"],["dc.bibliographiccitation.lastpage","284"],["dc.bibliographiccitation.volume","44"],["dc.contributor.author","Nehete, U. N."],["dc.contributor.author","Chandrasekhar, V."],["dc.contributor.author","Roesky, H. W."],["dc.contributor.author","Magull, Joerg"],["dc.date.accessioned","2018-11-07T08:33:32Z"],["dc.date.available","2018-11-07T08:33:32Z"],["dc.date.issued","2005"],["dc.identifier.doi","10.1002/anie.200460849"],["dc.identifier.isi","000226107200017"],["dc.identifier.uri","https://resolver.sub.uni-goettingen.de/purl?gro-2/17603"],["dc.notes.status","zu prüfen"],["dc.notes.submitter","Najko"],["dc.publisher","Wiley-v C H Verlag Gmbh"],["dc.relation.issn","1433-7851"],["dc.title","The formal conversion of SiOH protons into hydrides by germanium(II) species leads to the formation of the germanium(IV) hydride cluster [(RSiO3GeH)(4)]"],["dc.type","journal_article"],["dc.type.internalPublication","yes"],["dc.type.peerReviewed","yes"],["dc.type.status","published"],["dspace.entity.type","Publication"]]
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  • 2008Journal Article
    [["dc.bibliographiccitation.firstpage","94"],["dc.bibliographiccitation.journal","ARKIVOC"],["dc.bibliographiccitation.lastpage","115"],["dc.contributor.author","Khlebnikov, Alexander F."],["dc.contributor.author","Novikov, Mikhail S."],["dc.contributor.author","Dolgikh, Stanislav A."],["dc.contributor.author","Magull, Joerg"],["dc.date.accessioned","2018-11-07T11:19:27Z"],["dc.date.available","2018-11-07T11:19:27Z"],["dc.date.issued","2008"],["dc.description.abstract","1,3- vs. 1,5-Cyclization of azomethine ylides derived from 1-azabuta-1,3-dienes and difluoro- and dichlorocarbenes, leading to halogenosubstituted aziridine or pyrrole derivatives, was investigated. Calculations of the reaction profiles were carried out at the B3LYP/6-31G level to evaluate factors responsible for the predominant transformation pathways of the ylides."],["dc.description.sponsorship","Russian Foundation for Basic Research [08-0300112]"],["dc.identifier.isi","000263106800009"],["dc.identifier.uri","https://resolver.sub.uni-goettingen.de/purl?gro-2/55283"],["dc.notes.status","zu prüfen"],["dc.notes.submitter","Najko"],["dc.publisher","Arkat Usa Inc"],["dc.relation.issn","1424-6376"],["dc.title","1,3-vs. 1,5-Cyclization of azomethine ylides derived from 1-azabuta-1,3-dienes and difluoro- and dichlorocarbenes. Experimental and quantum-chemical study"],["dc.type","journal_article"],["dc.type.internalPublication","yes"],["dc.type.peerReviewed","yes"],["dc.type.status","published"],["dspace.entity.type","Publication"]]
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  • 2007Journal Article
    [["dc.bibliographiccitation.firstpage","2512"],["dc.bibliographiccitation.issue","14"],["dc.bibliographiccitation.journal","Angewandte Chemie International Edition"],["dc.bibliographiccitation.lastpage","2514"],["dc.bibliographiccitation.volume","46"],["dc.contributor.author","Nembenna, Sharanappa"],["dc.contributor.author","Roesky, Herbert W."],["dc.contributor.author","Nagendran, Selvarajan"],["dc.contributor.author","Hofmeister, Anja"],["dc.contributor.author","Magull, Joerg"],["dc.contributor.author","Wilbrandt, Peter-J."],["dc.contributor.author","Hahn, Matthias"],["dc.date.accessioned","2018-11-07T11:05:54Z"],["dc.date.available","2018-11-07T11:05:54Z"],["dc.date.issued","2007"],["dc.identifier.doi","10.1002/anie.200604447"],["dc.identifier.isi","000245371300034"],["dc.identifier.pmid","17318933"],["dc.identifier.uri","https://resolver.sub.uni-goettingen.de/purl?gro-2/52173"],["dc.notes.status","zu prüfen"],["dc.notes.submitter","Najko"],["dc.publisher","Wiley-v C H Verlag Gmbh"],["dc.relation.issn","1433-7851"],["dc.title","A well-defined hydrocarbon-soluble calcium monofluoride, [{LCaF(thf)}(2)]: The application of soluble calcium derivatives for surface coating"],["dc.type","journal_article"],["dc.type.internalPublication","yes"],["dc.type.peerReviewed","yes"],["dc.type.status","published"],["dspace.entity.type","Publication"]]
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  • 2007Journal Article
    [["dc.bibliographiccitation.firstpage","7594"],["dc.bibliographiccitation.issue","18"],["dc.bibliographiccitation.journal","Inorganic Chemistry"],["dc.bibliographiccitation.lastpage","7600"],["dc.bibliographiccitation.volume","46"],["dc.contributor.author","Mandal, Swadhin K."],["dc.contributor.author","Gurubasavaraj, Prabhuodeyara M."],["dc.contributor.author","Roesky, Herbert W."],["dc.contributor.author","Oswald, Rainer B."],["dc.contributor.author","Magull, Joerg"],["dc.contributor.author","Ringe, Arne"],["dc.date.accessioned","2018-11-07T10:58:40Z"],["dc.date.available","2018-11-07T10:58:40Z"],["dc.date.issued","2007"],["dc.description.abstract","We report a facile route to the first molecular compounds with the Al - O - M - O - Al ( M) Ti, Zr) structural motif. Synthesis of L( Me) Al( mu- O) M( NMe2) 2( mu- O) Al( Me) L [ L) CH {N( Ar)( CMe)} 2, Ar) 2,6- i Pr2C6H3; M) Ti ( 7), Zr ( 8)] was accomplished by reacting the monometallic hydroxide precursor L( Me) Al( OH) ( 1) with Ti( NMe2) 4 or Zr( NMe2) 4 under elimination of Me2NH in good yield. The crystal structural data confirm the trimetallic Al - O - M - O - Al core in both 7 and 8. Preliminary investigation on catalytic activity of these complexes reveals low activity of these complexes in ethylene polymerization as compared to the related oxygen- bridged metallocene- based heterobimetallic complexes L( Me) Al( mu- O) M( Me) Cp-2 ( M) Ti, Zr) which could be attributed to the relatively lower stability of the supposed cationic intermediate as revealed by DFT calculations."],["dc.identifier.doi","10.1021/ic701063v"],["dc.identifier.isi","000248984500051"],["dc.identifier.pmid","17685512"],["dc.identifier.uri","https://resolver.sub.uni-goettingen.de/purl?gro-2/50516"],["dc.notes.status","zu prüfen"],["dc.notes.submitter","Najko"],["dc.publisher","Amer Chemical Soc"],["dc.relation.issn","0020-1669"],["dc.title","Synthesis, structural characterization, and theoretical investigation of compounds containing an Al-O-M-O-Al (M = Ti, Zr) Core"],["dc.type","journal_article"],["dc.type.internalPublication","yes"],["dc.type.peerReviewed","yes"],["dc.type.status","published"],["dspace.entity.type","Publication"]]
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  • 2004Journal Article
    [["dc.bibliographiccitation.firstpage","4046"],["dc.bibliographiccitation.issue","20"],["dc.bibliographiccitation.journal","European Journal of Inorganic Chemistry"],["dc.bibliographiccitation.lastpage","4051"],["dc.contributor.author","Zhu, H. P."],["dc.contributor.author","Chai, J. F."],["dc.contributor.author","Stasch, A."],["dc.contributor.author","Roesky, H. W."],["dc.contributor.author","Blunck, T."],["dc.contributor.author","Vidovic, D."],["dc.contributor.author","Magull, Joerg"],["dc.contributor.author","Schmidt, H. G."],["dc.contributor.author","Noltemeyer, M."],["dc.date.accessioned","2018-11-07T10:44:46Z"],["dc.date.available","2018-11-07T10:44:46Z"],["dc.date.issued","2004"],["dc.description.abstract","The solid-state reaction of LAl and imidazol-2-ylidene at elevated temperature (120 degreesC) yielded the aluminum monohydride N-heterocyclic carbene adduct [(HC[C(CH2)NAr] (CMeNAr)}AIH-(CN(R)C2Me2N(R)}] [R = iPr (1), Me (2)]. Compounds 1 and 2 have been characterized by spectroscopic (IR, and H-1 and C-13 NMR), mass spectrometric, and elemental analyses, and I was further characterized by Xray structural analysis. These experimental data indicate that the AI-H bond is formed by hydrogen migration from one of the methyl groups of the beta-diketiminato ligand backbone. The reaction of LAl with two equivalents of diphenyldiazomethane afforded the diiminylaluminum compound LAl(N= CPh2)(2) (3), while an excess of diphenyldiazomethane resulted in the formation of Ph2C=N-N=CPh2. This suggests that Ph2C=N-N=CPh2 is initially generated and then reacts further by oxidative addition to yield 3. The X-ray structural analysis reveals that compound 3 contains the shortest Al-N-iminyl bond among those with a four-coordinate aluminum center."],["dc.identifier.doi","10.1002/ejic.200400159"],["dc.identifier.isi","000225781600011"],["dc.identifier.uri","https://resolver.sub.uni-goettingen.de/purl?gro-2/47343"],["dc.notes.status","zu prüfen"],["dc.notes.submitter","Najko"],["dc.publisher","Wiley-v C H Verlag Gmbh"],["dc.relation.issn","1434-1948"],["dc.title","Reactions of the aluminum(I) monomer LAl [L = HC{(CMe)(NAr)}(2); Ar=2,6-iPr(2)C(6)H(3)]with imidazol-2-ylidene and diphenyldiazomethane. A hydrogen transfer from the L ligand to the central aluminum atom and formation of the diiminylaluminum compound LAl(N=CPh2)(2)"],["dc.type","journal_article"],["dc.type.internalPublication","yes"],["dc.type.peerReviewed","yes"],["dc.type.status","published"],["dspace.entity.type","Publication"]]
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  • 2007Journal Article
    [["dc.bibliographiccitation.issue","35"],["dc.bibliographiccitation.journal","ChemInform"],["dc.bibliographiccitation.volume","38"],["dc.contributor.author","Suennemann, Hans Wolf"],["dc.contributor.author","Hofmeister, Anja"],["dc.contributor.author","Magull, Joerg"],["dc.contributor.author","de Meijere, Armin"],["dc.date.accessioned","2021-12-08T12:29:35Z"],["dc.date.available","2021-12-08T12:29:35Z"],["dc.date.issued","2007"],["dc.identifier.doi","10.1002/chin.200735180"],["dc.identifier.uri","https://resolver.sub.uni-goettingen.de/purl?gro-2/96135"],["dc.language.iso","en"],["dc.notes.intern","DOI-Import GROB-476"],["dc.relation.eissn","1522-2667"],["dc.relation.issn","0931-7597"],["dc.rights.uri","http://doi.wiley.com/10.1002/tdm_license_1.1"],["dc.title","Stille—Heck Coupling Sequences Applied in a Versatile New Access to Steroid Skeletons."],["dc.type","journal_article"],["dc.type.internalPublication","yes"],["dspace.entity.type","Publication"]]
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  • 2006Journal Article
    [["dc.bibliographiccitation.firstpage","5485"],["dc.bibliographiccitation.issue","24"],["dc.bibliographiccitation.journal","European Journal of Organic Chemistry"],["dc.bibliographiccitation.lastpage","5494"],["dc.contributor.author","Marradi, Marco"],["dc.contributor.author","Brandi, Alberto"],["dc.contributor.author","Magull, Joerg"],["dc.contributor.author","Schill, Heiko"],["dc.contributor.author","de Meijere, Armin"],["dc.date.accessioned","2018-11-07T08:51:08Z"],["dc.date.available","2018-11-07T08:51:08Z"],["dc.date.issued","2006"],["dc.description.abstract","Intramolecular cycloadditions of various nitrone functionalities with different substituents (R = Me, Bn, tBu) at the nitrogen atom tethered to a bicyclopropylidene unit through a two-carbon chain led to cis-fused tricyclic isoxazolidines (3-alkyl-3,3a,4,5,5a,6-hexahydrocyclopropa[2,3]cyclopenta[1,2-c]isoxazolespiro[1,1']cyclopropanes) 26 in 42-58% yield with complete regio- and diastereoselectivity. The thermal rearrangement of the cycloadducts 26 under neutral conditions afforded the corresponding tricyclic tetrahydropyridones 27 (52-53%). The analogous starting materials with a three-carbon tether, the 4-(bicyclopropyliden-2-yl)butylidenenitrones furnished tricyclic isoxazolidines 28 (54-58%) and tetrahydropyridones 29 (55-64%) by subsequent thermal rearrangement. Under acidic conditions (TFA), the cycloadducts 26 and 28 underwent fragmentative rearrangements to afford the tricyclic beta-lactams 30 and 32 (50-66%), respectively, of which the former suffered amide-bond cleavage in situ to provide the corresponding N-trifluoroacetyl beta-amino acid derivatives 31 (68-71%). ((C) Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2006)."],["dc.identifier.doi","10.1002/ejoc.200600417"],["dc.identifier.isi","000243078000009"],["dc.identifier.uri","https://resolver.sub.uni-goettingen.de/purl?gro-2/21858"],["dc.notes.status","zu prüfen"],["dc.notes.submitter","Najko"],["dc.publisher","Wiley-v C H Verlag Gmbh"],["dc.relation.issn","1434-193X"],["dc.title","New highly strained multifunctional heterocycles by intramolecular cycloadditions of nitrones to bicyclopropylidene moieties"],["dc.type","journal_article"],["dc.type.internalPublication","yes"],["dc.type.peerReviewed","yes"],["dc.type.status","published"],["dspace.entity.type","Publication"]]
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  • 2005Journal Article
    [["dc.bibliographiccitation.firstpage","1199"],["dc.bibliographiccitation.issue","5"],["dc.bibliographiccitation.journal","Inorganic Chemistry"],["dc.bibliographiccitation.lastpage","1201"],["dc.bibliographiccitation.volume","44"],["dc.contributor.author","Kumar, S. S."],["dc.contributor.author","Singh, S."],["dc.contributor.author","Roesky, H. W."],["dc.contributor.author","Magull, Joerg"],["dc.date.accessioned","2018-11-07T11:16:49Z"],["dc.date.available","2018-11-07T11:16:49Z"],["dc.date.issued","2005"],["dc.description.abstract","The reaction between beta-diketiminato-stabilized aluminum dihydride LAIH(2) and (tB)uOOH leads to the formation of a pentacoordinated tert-butylperoxo aluminum compound."],["dc.identifier.doi","10.1021/ic048336n"],["dc.identifier.isi","000227346300016"],["dc.identifier.pmid","15732957"],["dc.identifier.uri","https://resolver.sub.uni-goettingen.de/purl?gro-2/54682"],["dc.notes.status","zu prüfen"],["dc.notes.submitter","Najko"],["dc.publisher","Amer Chemical Soc"],["dc.relation.issn","0020-1669"],["dc.title","Reaction of LAIH(2) with tert-butyl hydrogen peroxide under C-H bond activation and substitution leads to the formation of a pentacoordinated tert-butylperoxo aluminum compound"],["dc.type","journal_article"],["dc.type.internalPublication","yes"],["dc.type.peerReviewed","yes"],["dc.type.status","published"],["dspace.entity.type","Publication"]]
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