Schneck, Felix

[["dc.bibliographiccitation.artnumber","chem.202101705"],["dc.bibliographiccitation.journal","Chemistry: a European Journal"],["dc.contributor.author","Sang, Sier"],["dc.contributor.author","Unruh, Tobias"],["dc.contributor.author","Demeshko, Serhiy"],["dc.contributor.author","Domenianni, Luis"],["dc.contributor.author","van Leest, Nicolaas"],["dc.contributor.author","Marquetand, Philipp"],["dc.contributor.author","Schneck, Felix"],["dc.contributor.author","Würtele, Christian"],["dc.contributor.author","de Zwaart, Felix"],["dc.contributor.author","Schneider, Sven"],["dc.date.accessioned","2021-07-05T14:57:19Z"],["dc.date.available","2021-07-05T14:57:19Z"],["dc.date.issued","2021"],["dc.identifier.doi","10.1002/chem.202101705"],["dc.identifier.uri","https://resolver.sub.uni-goettingen.de/purl?gro-2/87620"],["dc.language.iso","en"],["dc.notes.intern","DOI-Import GROB-441"],["dc.relation.eissn","1521-3765"],["dc.relation.issn","0947-6539"],["dc.title","Photo‐Initiated Cobalt Catalyzed Radical Olefin Hydrogenation"],["dc.type","journal_article"],["dc.type.internalPublication","yes"],["dspace.entity.type","Publication"]]

[["dc.bibliographiccitation.firstpage","14482"],["dc.bibliographiccitation.issue","44"],["dc.bibliographiccitation.journal","Angewandte Chemie International Edition"],["dc.bibliographiccitation.lastpage","14487"],["dc.bibliographiccitation.volume","57"],["dc.contributor.author","Schneck, Felix"],["dc.contributor.author","Schendzielorz, Florian S."],["dc.contributor.author","Hatami, Nareh"],["dc.contributor.author","Finger, Markus"],["dc.contributor.author","Würtele, Christian"],["dc.contributor.author","Schneider, Sven"],["dc.date.accessioned","2019-07-09T11:51:20Z"],["dc.date.available","2019-07-09T11:51:20Z"],["dc.date.issued","2018"],["dc.identifier.doi","10.1002/anie.201803396"],["dc.identifier.purl","https://resolver.sub.uni-goettingen.de/purl?gs-1/16108"],["dc.identifier.uri","https://resolver.sub.uni-goettingen.de/purl?gro-2/59930"],["dc.language.iso","en"],["dc.notes.intern","Merged from goescholar"],["dc.relation","info:eu-repo/grantAgreement/EC/H2020/646747/EU//N2FEED"],["dc.relation","SFB 1073: Kontrolle von Energiewandlung auf atomaren Skalen"],["dc.relation","SFB 1073 | Topical Area C | C07 Kontrolle Reaktivität hydridischer Photokatalysatoren"],["dc.relation.issn","1433-7851"],["dc.rights","Goescholar"],["dc.rights.uri","https://goescholar.uni-goettingen.de/licenses"],["dc.subject.ddc","540"],["dc.title","Photochemically Driven Reverse Water-Gas Shift at Ambient Conditions mediated by a Nickel Pincer Complex"],["dc.type","journal_article"],["dc.type.internalPublication","yes"],["dc.type.subtype","original_ja"],["dc.type.version","published_version"],["dspace.entity.type","Publication"]]

[["dc.bibliographiccitation.artnumber","1161"],["dc.bibliographiccitation.firstpage","1"],["dc.bibliographiccitation.issue","1"],["dc.bibliographiccitation.journal","Nature Communications"],["dc.bibliographiccitation.lastpage","8"],["dc.bibliographiccitation.volume","9"],["dc.contributor.author","Schneck, Felix"],["dc.contributor.author","Ahrens, Jennifer"],["dc.contributor.author","Finger, Markus"],["dc.contributor.author","Stückl, Andrea Claudia"],["dc.contributor.author","Würtele, Christian"],["dc.contributor.author","Schwarzer, Dirk"],["dc.contributor.author","Schneider, Sven"],["dc.date.accessioned","2019-07-09T11:45:18Z"],["dc.date.available","2019-07-09T11:45:18Z"],["dc.date.issued","2018"],["dc.description.abstract","Direct hydrogenation of CO2 to CO, the reverse water-gas shift reaction, is an attractive route to CO2 utilization. However, the use of molecular catalysts is impeded by the general reactivity of metal hydrides with CO2. Insertion into M-H bonds results in formates (MO(O)CH), whereas the abnormal insertion to the hydroxycarbonyl isomer (MC(O)OH), which is the key intermediate for CO-selective catalysis, has never been directly observed. We here report that the selectivity of CO2 insertion into a Ni-H bond can be inverted from normal to abnormal insertion upon switching from thermal to photochemical conditions. Mechanistic examination for abnormal insertion indicates photochemical N-H reductive elimination as the pivotal step that leads to an umpolung of the hydride ligand. This study conceptually introduces metal-ligand cooperation for selectivity control in photochemical transformations."],["dc.identifier.doi","10.1038/s41467-018-03239-3"],["dc.identifier.pmid","29563551"],["dc.identifier.purl","https://resolver.sub.uni-goettingen.de/purl?gs-1/15100"],["dc.identifier.uri","https://resolver.sub.uni-goettingen.de/purl?gro-2/59204"],["dc.language.iso","en"],["dc.notes.intern","Merged from goescholar"],["dc.relation","info:eu-repo/grantAgreement/EC/H2020/646747/EU//N2FEED"],["dc.relation","SFB 1073: Kontrolle von Energiewandlung auf atomaren Skalen"],["dc.relation","SFB 1073 | Topical Area C | C07 Kontrolle Reaktivität hydridischer Photokatalysatoren"],["dc.relation.issn","2041-1723"],["dc.rights","CC BY 4.0"],["dc.rights.uri","https://creativecommons.org/licenses/by/4.0"],["dc.subject.ddc","540"],["dc.title","The elusive abnormal CO2 insertion enabled by metal-ligand cooperative photochemical selectivity inversion"],["dc.type","journal_article"],["dc.type.internalPublication","yes"],["dc.type.subtype","original_ja"],["dc.type.version","published_version"],["dspace.entity.type","Publication"]]

[["dc.bibliographiccitation.journal","Zeitschrift für anorganische und allgemeine Chemie"],["dc.contributor.author","Schneck, Felix"],["dc.contributor.author","Finger, Markus"],["dc.contributor.author","Siewert, Inke"],["dc.contributor.author","Schneider, Sven"],["dc.date.accessioned","2021-06-01T09:42:35Z"],["dc.date.available","2021-06-01T09:42:35Z"],["dc.date.issued","2021"],["dc.description.abstract","Metal coordination can substantially weaken the bond strength of X−H bonds in coordinated ligands. Despite the importance for redox catalysis, this phenomenon is surprisingly scarcely examined for C−H bonds of organometallic compounds. We here report a nickel(I) pincer complex with a remote methylene group in the ligand backbone that exhibits an unusually solvent dependent C−H bond dissociation free energy (BDFEC−H). Structural and thermochemical characterization in MeCN and THF indicates that the BDFEC−H strongly depends on solvent binding to the metal within the NiII/NiI redox couple."],["dc.identifier.doi","10.1002/zaac.202100077"],["dc.identifier.uri","https://resolver.sub.uni-goettingen.de/purl?gro-2/85295"],["dc.language.iso","en"],["dc.notes.intern","DOI-Import GROB-425"],["dc.relation","SFB 1073: Kontrolle von Energiewandlung auf atomaren Skalen"],["dc.relation","SFB 1073 | Topical Area C | C07 Kontrolle Reaktivität hydridischer Photokatalysatoren"],["dc.relation.eissn","1521-3749"],["dc.relation.issn","0044-2313"],["dc.rights","CC BY-NC 4.0"],["dc.title","Solvent dependent C−H Bond Strength in a Nickel Pincer Complex"],["dc.type","journal_article"],["dc.type.internalPublication","yes"],["dc.type.subtype","original_ja"],["dc.type.version","published_version"],["dspace.entity.type","Publication"]]

[["dc.bibliographiccitation.firstpage","33"],["dc.bibliographiccitation.issue","1"],["dc.bibliographiccitation.journal","Chemistry"],["dc.bibliographiccitation.lastpage","37"],["dc.bibliographiccitation.volume","23"],["dc.contributor.author","Schneck, Felix"],["dc.contributor.author","Finger, Markus"],["dc.contributor.author","Tromp, Moniek"],["dc.contributor.author","Schneider, Sven"],["dc.date.accessioned","2019-07-09T11:42:58Z"],["dc.date.available","2019-07-09T11:42:58Z"],["dc.date.issued","2016"],["dc.description.abstract","The synthesis of the divinylamido PNP nickel(II) complex [NiBr{N(CHCHPtBu2)2}] is reported. This compound exhibits reversible, ligand centered oxidation and protonation reactions. The resulting pincer chemical non-innocence can be utilized for benzylic C-H hydrogen atom abstraction. The thermochemistry and kinetics of hydrogen atom transfer were examined."],["dc.identifier.doi","10.1002/chem.201604407"],["dc.identifier.purl","https://resolver.sub.uni-goettingen.de/purl?gs-1/14024"],["dc.identifier.uri","https://resolver.sub.uni-goettingen.de/purl?gro-2/58796"],["dc.language.iso","en"],["dc.notes.intern","Merged from goescholar"],["dc.notes.intern","In goescholar not merged with http://resolver.sub.uni-goettingen.de/purl?gs-1/15306 but duplicate"],["dc.relation","info:eu-repo/grantAgreement/EC/H2020/646747/EU/N2 as Chemical Feedstock – Synthetic Nitrogen Fixation beyond Haber-Bosch/N2FEED"],["dc.rights","Goescholar"],["dc.rights.access","openAccess"],["dc.rights.uri","https://goescholar.uni-goettingen.de/licenses"],["dc.subject.ddc","540"],["dc.title","Chemical Non-Innocence of an aliphatic PNP Pincer Ligand"],["dc.type","journal_article"],["dc.type.internalPublication","yes"],["dc.type.version","submitted_version"],["dspace.entity.type","Publication"]]