Herbst-Irmer, Regine

[["dc.bibliographiccitation.firstpage","1774"],["dc.bibliographiccitation.issue","12"],["dc.bibliographiccitation.journal","Angewandte Chemie / International Edition"],["dc.bibliographiccitation.lastpage","1776"],["dc.bibliographiccitation.volume","32"],["dc.contributor.author","Armstrong, David R."],["dc.contributor.author","Herbst-Irmer, Regine"],["dc.contributor.author","Kuhn, Annja"],["dc.contributor.author","Moncrieff, David"],["dc.contributor.author","Paver, Michael A."],["dc.contributor.author","Russell, Christopher A."],["dc.contributor.author","Stalke, Dietmar"],["dc.contributor.author","Steiner, Alexander"],["dc.contributor.author","Wright, Dominic S."],["dc.date.accessioned","2019-07-09T11:52:15Z"],["dc.date.available","2019-07-09T11:52:15Z"],["dc.date.issued","1993"],["dc.description.abstract","A bent thallocene anion is found in complexes 1 and 2, which are prepared by the reaction of [CpTl] and [Cp2Mg] (for 1) or [CpLi] (for 2) and N,N,N,N,N-pentamethyldiethylenediamine (PMDETA). The [(5-Cp)2Tl]- anion is isoelectronic and isostructural with stannocene. Ab initio calculations show that the bent structure with CS symmetry is only marginally more stable than the linear conformer with D5h symmetry."],["dc.identifier.doi","10.1002/anie.199317741"],["dc.identifier.purl","https://resolver.sub.uni-goettingen.de/purl?goescholar/3390"],["dc.identifier.uri","https://resolver.sub.uni-goettingen.de/purl?gro-2/60132"],["dc.language.iso","de"],["dc.notes.intern","Merged from goescholar"],["dc.rights","Goescholar"],["dc.rights.uri","https://goescholar.uni-goettingen.de/licenses"],["dc.subject.ddc","540"],["dc.title","The Bis(cyclopentadienyl)thallate(I) Anion Isoelectronic with Stannocene"],["dc.title.alternative","Bis(cyclopentadienyl)thallat(I), ein mit Stannocen isoelektronisches Anion"],["dc.type","journal_article"],["dc.type.internalPublication","yes"],["dc.type.version","published_version"],["dspace.entity.type","Publication"]]

[["dc.bibliographiccitation.firstpage","41"],["dc.bibliographiccitation.issue","15/16"],["dc.bibliographiccitation.journal","Zeitschrift für Anorganische und Allgemeine Chemie"],["dc.bibliographiccitation.lastpage","47"],["dc.bibliographiccitation.volume","620"],["dc.contributor.author","Labahn, Dieter"],["dc.contributor.author","Bohnen, Frank-Michael"],["dc.contributor.author","Herbst-Irmer, Regine"],["dc.contributor.author","Pohl, Ehmke"],["dc.contributor.author","Stalke, Dietmar"],["dc.contributor.author","Roesky, Herbert W."],["dc.date.accessioned","2019-07-09T11:52:16Z"],["dc.date.available","2019-07-09T11:52:16Z"],["dc.date.issued","1994"],["dc.description.abstract","RfSeH 1 entsteht in einer Eintopfsynthese bei der Reaktion von RfLi [Rf = 2,4,6-Tris(trifluormethyl)phenyl] mit elementarem Selen und anschließender Umsetzung mit HBF4. Mit 1 konnte zum ersten Mal die Kristallstruktur eines Selenans bestimmt werden. Bei der Umsetzung von 1 mit M[N(SiMe3)2]2 (M = Zn, Pb) im Molverhältnis 2:1 erhält man die Metallselenophenolate Zn(SeRf)2 · HN(SiMe3)2 2 und [Pb(SeRf)2]2 3. 2 kristallisiert als Hexamethyldisilazan-Addukt, während 3 als Dimer vorliegt. Translated abstract: RfSeH 1 is obtained in a single pot reaction of RfLi [Rf = 2,4,6-tris(trifluoromethyl)phenyl] with elemental selenium and following treatment with HBF4. 1 gave the first crystal structure of a selenane. Reaction of 1 with M[N(SiMe3)2]2 (M = Zn, Pb) in the molar ratio of 2:1 yielded the metal selenophenolates"],["dc.identifier.doi","10.1002/zaac.19946200107"],["dc.identifier.purl","https://resolver.sub.uni-goettingen.de/purl?goescholar/3401"],["dc.identifier.uri","https://resolver.sub.uni-goettingen.de/purl?gro-2/60139"],["dc.language.iso","de"],["dc.notes.intern","Merged from goescholar"],["dc.rights","Goescholar"],["dc.rights.uri","https://goescholar.uni-goettingen.de/licenses"],["dc.subject.ddc","540"],["dc.title","Erste Kristallstruktur eines Selenans; Metall(II)-Komplexe mit dem 2,4,6-Tris(trifluormethyl)selenophenolat-Liganden"],["dc.title.alternative","The First Structure of a Selenane; Metal(II) Complexes with the 2,4,6-Tris(trifluoromethyl)-selenophenolato Ligand"],["dc.type","journal_article"],["dc.type.internalPublication","yes"],["dc.type.version","published_version"],["dspace.entity.type","Publication"]]

[["dc.bibliographiccitation.firstpage","2694"],["dc.bibliographiccitation.issue","12"],["dc.bibliographiccitation.journal","Inorganic Chemistry"],["dc.bibliographiccitation.lastpage","2698"],["dc.bibliographiccitation.volume","32"],["dc.contributor.author","Heine, Andreas"],["dc.contributor.author","Herbst-Irmer, Regine"],["dc.contributor.author","Sheldrick, George M."],["dc.contributor.author","Stalke, Dietmar"],["dc.date.accessioned","2019-07-09T11:52:13Z"],["dc.date.available","2019-07-09T11:52:13Z"],["dc.date.issued","1993"],["dc.description.abstract","The crystal structures of (MesSi),Si.THF (a = b = 12.310(1) A, c = 17.308(2) A, tetragonal, space group P4/ncc (No. 130), Z = 4), [(Me3Si)&i][(Me3Si)3SiLi(THF)3](a~ = b = 15.146(8) A, c = 21.338(10) A, trigonal, space groupP3cl (No. 165), Z = 2), (Me3Si)3SiLi(THF)3 (a = b = 31.342(4) A, c = 22.000(6) A, rhombohedral, space groupR3c (No. 161), Z = 24), and (Me3Si)3SiSi(SiMe3)3aTHF (a = 11.360(3) A, b = 17.131(6) A, c = 18.952(6) A, 0 = 91.21(3)', monoclinic, space group P21/c (No. 14), Z = 4), have been determined by low-temperature X-ray analysis. Whereas the small S i S i S i angle in (tris(trimethylsily1)silyl)lithium of 102.1 O supports the ionic character of the Si-Li bond, there must be at least some covalent contribution leading to a J[%,7Li] coupling constant of 38.6 Hz. A modified preparation for (Me3si)~siLi(THF)is~ reported giving the pure product rather than the cocrystallization product [(Me3Si)4Si] [(Me3Si)3SiLi(THF)3]2, where the starting material is still present in the ratio 1:2. The pure product is far more reactive than the cocrystallized material and is as pyrophoric as 'BuLi powder."],["dc.identifier.doi","10.1021/ic00064a019"],["dc.identifier.purl","https://resolver.sub.uni-goettingen.de/purl?goescholar/3369"],["dc.identifier.uri","https://resolver.sub.uni-goettingen.de/purl?gro-2/60120"],["dc.language.iso","en"],["dc.notes.intern","Merged from goescholar"],["dc.rights","Goescholar"],["dc.rights.uri","https://goescholar.uni-goettingen.de/licenses"],["dc.subject.ddc","540"],["dc.title","Structural characterization of two modifications of tris(tetrahydrofuran)(tris(trimethylsilyl)silyl)lithium: a compound with a silicon-29-lithium-7 NMR coupling"],["dc.type","journal_article"],["dc.type.internalPublication","yes"],["dc.type.version","published_version"],["dspace.entity.type","Publication"]]

[["dc.bibliographiccitation.firstpage","577"],["dc.bibliographiccitation.issue","5"],["dc.bibliographiccitation.journal","Angewandte Chemie"],["dc.bibliographiccitation.lastpage","578"],["dc.bibliographiccitation.volume","106"],["dc.contributor.author","Liu, Feng-Quan"],["dc.contributor.author","Kuhn, Annja"],["dc.contributor.author","Herbst-Irmer, Regine"],["dc.contributor.author","Stalke, Dietmar"],["dc.contributor.author","Roesky, Herbert W."],["dc.date.accessioned","2019-07-09T11:52:17Z"],["dc.date.available","2019-07-09T11:52:17Z"],["dc.date.issued","1994"],["dc.description.abstract","Zentrale NaF- und MgF2,-Gerüste enthalten die bei der Reaktion von [Cp TiF3](Cp = C5Me5) mit elementarem Natrium bzw. Magnesium gebildeten Titelverbindungen. Bei diesen Umsetzungen wird TiIV zu TiIII reduziert. Die Cp Ti-Einheiten dienen als metallorganische Hülle um den käfigartigen Kern und sorgen für gute Löslichkeit."],["dc.identifier.doi","10.1002/ange.19941060508"],["dc.identifier.purl","https://resolver.sub.uni-goettingen.de/purl?goescholar/3404"],["dc.identifier.uri","https://resolver.sub.uni-goettingen.de/purl?gro-2/60141"],["dc.language.iso","de"],["dc.notes.intern","Merged from goescholar"],["dc.rights","Goescholar"],["dc.rights.uri","https://goescholar.uni-goettingen.de/licenses"],["dc.subject.ddc","540"],["dc.title","Molekulare Festkörper als Liganden in der Organometallchemie: [CpTi6Na7F19 · 2.5thf] (Cp = C5Me5) und [CpTi4Mg2F12 · 7thf], Bindeglieder zwischen ionischen Feststoffen und metallorganischen Verbindungen"],["dc.type","journal_article"],["dc.type.internalPublication","yes"],["dc.type.version","published_version"],["dspace.entity.type","Publication"]]

[["dc.bibliographiccitation.firstpage","363"],["dc.bibliographiccitation.issue","3"],["dc.bibliographiccitation.journal","Acta Crystallographica / B"],["dc.bibliographiccitation.lastpage","373"],["dc.bibliographiccitation.volume","50"],["dc.contributor.author","Heine, Andreas"],["dc.contributor.author","Herbst-Irmer, Regine"],["dc.contributor.author","Stalke, Dietmar"],["dc.contributor.author","Kühnle, Wolfgang"],["dc.contributor.author","Zachariasse, Klaas A."],["dc.date.accessioned","2009-07-03T12:36:17Z"],["dc.date.accessioned","2021-10-27T13:12:07Z"],["dc.date.available","2009-07-03T12:36:17Z"],["dc.date.available","2021-10-27T13:12:07Z"],["dc.date.issued","1994"],["dc.description.abstract","The amino N atom in 4-aminobenzonitrile (ABN) and 4-(dimethylamino)benzonitrile (DMABN) has a pyramidal character, with values of 34(3) and 11.9 (3) c~, respectively, for the angle between the planes of the amino group and the phenyl ring. In 3,5-dimethyl-4-(dimethylamino)benzonitrile (MMD) at 173 K, the dimethylamino group is twisted over an angle of 59.3 (2) \"~ with respect to the phenyl plane. In addition, the amino N(1) atom is not located in the plane of the phenyl ring, with an out-of-plane displacement of 0.117 (5)/~. The N-phenyl bond length in MMD of 1.414 (3)/~ is larger that that in the four other aminobenzonitriles, for which an average bond length of 1.367,~ is found. With DMABN, the crystal structure consists of stacks with an alternating orientation of the molecules. In the crystals of ABN, 3,5-dimethyl-4-(methylamino)benzonitrile (MHD) and 4-amino-3,5-dimethylbenzonitrile (HHD), hydrogen bonding is an important structural element. In ABN and MHD, hydrogen bonds are formed between an amino H atom and the cyano N atom of adjacent molecules. In HHD, each H atom is linked to a cyano N atom of two different neighbouring molecules, in a layered structure consisting of squares and octagons. Temperature-dependent solid-solid phase transitions are observed with all five aminobenzonitriles studied here. Crystals of the low-temperature phase could only be obtained from ABN, with lattice constants which are considerably different from those observed at room temperature."],["dc.format.mimetype","application/pdf"],["dc.identifier.doi","10.1107/S0108768193008523"],["dc.identifier.purl","https://resolver.sub.uni-goettingen.de/purl?goescholar/3406"],["dc.identifier.uri","https://resolver.sub.uni-goettingen.de/purl?gro-2/91660"],["dc.language.iso","en"],["dc.notes.intern","Migrated from goescholar"],["dc.relation.orgunit","Fakultät für Chemie"],["dc.rights","Goescholar"],["dc.rights.access","openAccess"],["dc.rights.uri","https://goescholar.uni-goettingen.de/licenses"],["dc.subject","anorganische Chemie"],["dc.subject.ddc","540"],["dc.title","Structure and crystal packing of 4-aminobenzonitriles and 4-amino-3,5-dimethylbenzonitriles at various temperatures"],["dc.type","journal_article"],["dc.type.internalPublication","yes"],["dc.type.peerReviewed","yes"],["dc.type.version","published_version"],["dspace.entity.type","Publication"]]

[["dc.bibliographiccitation.firstpage","555"],["dc.bibliographiccitation.issue","5"],["dc.bibliographiccitation.journal","Angewandte Chemie / International Edition"],["dc.bibliographiccitation.lastpage","556"],["dc.bibliographiccitation.volume","33"],["dc.contributor.author","Liu, Feng-Quan"],["dc.contributor.author","Kuhn, Annja"],["dc.contributor.author","Herbst-Irmer, Regine"],["dc.contributor.author","Stalke, Dietmar"],["dc.contributor.author","Roesky, Herbert W."],["dc.date.accessioned","2019-07-09T11:52:17Z"],["dc.date.available","2019-07-09T11:52:17Z"],["dc.date.issued","1994"],["dc.description.abstract","Central NaF and MgF2 frameworks are present in the title compounds obtained from the reaction of [Cp TiF3] (Cp C5Me5) with elemental sodium and magnesium, respectively. In these reactions TiIV is reduced to TiIII. The Cp Ti units function as organometallics shields around the cagelike core and are responsible for the high solubility of the compounds."],["dc.identifier.doi","10.1002/anie.199405551"],["dc.identifier.purl","https://resolver.sub.uni-goettingen.de/purl?goescholar/3405"],["dc.identifier.uri","https://resolver.sub.uni-goettingen.de/purl?gro-2/60142"],["dc.language.iso","en"],["dc.notes.intern","Merged from goescholar"],["dc.rights","Goescholar"],["dc.rights.uri","https://goescholar.uni-goettingen.de/licenses"],["dc.subject.ddc","540"],["dc.title","Molecular Solids as Ligands in Organometallic Chemistry: [CpTi6Na7F19·2.5thf] (Cp C5Me5) and [CpTi4Mg2F12·7thf], Links Between Ionic Solids and Organometallic Compounds"],["dc.type","journal_article"],["dc.type.internalPublication","yes"],["dc.type.version","published_version"],["dspace.entity.type","Publication"]]

[["dc.bibliographiccitation.firstpage","1621"],["dc.bibliographiccitation.issue","15/16"],["dc.bibliographiccitation.journal","Angewandte Chemie / International Edition"],["dc.bibliographiccitation.lastpage","1623"],["dc.bibliographiccitation.volume","33"],["dc.contributor.author","Saalfrank, Rolf W."],["dc.contributor.author","Burak, Roman"],["dc.contributor.author","Breit, Alexandra"],["dc.contributor.author","Herbst-Irmer, Regine"],["dc.contributor.author","Stalke, Dietmar"],["dc.contributor.author","Daub, Jörg"],["dc.contributor.author","Porsch, Michael"],["dc.contributor.author","Bill, Eckhard"],["dc.contributor.author","Müther, Markus"],["dc.contributor.author","Trautwein, Alfred X."],["dc.date.accessioned","2019-07-09T11:52:19Z"],["dc.date.available","2019-07-09T11:52:19Z"],["dc.date.issued","1994"],["dc.description.abstract","In a simple one-pot reaction the host-guest compounds 1 (white spheres FeIII; black = FeII; gray = NH; angled rods = 2: R = Me, Et) are accessible in gram quantities by self-assembly. They are the only fully characterized redox isomers whose cyclic voltammograms display four quasi-reversible waves and whose mixed-valent character has been established by Mössbauer spectra. The endohedral complexation of one NH ion in 1 has been confirmed by X-ray crystallography."],["dc.identifier.doi","10.1002/anie.199416211"],["dc.identifier.purl","https://resolver.sub.uni-goettingen.de/purl?goescholar/3418"],["dc.identifier.uri","https://resolver.sub.uni-goettingen.de/purl?gro-2/60154"],["dc.language.iso","en"],["dc.notes.intern","Merged from goescholar"],["dc.rights","Goescholar"],["dc.rights.uri","https://goescholar.uni-goettingen.de/licenses"],["dc.subject.ddc","540"],["dc.title","Mixed-Valence, Tetranuclear Iron Chelate Complexes as Endoreceptors: Charge Compensation Through Inclusion of Cations"],["dc.type","journal_article"],["dc.type.internalPublication","yes"],["dc.type.version","published_version"],["dspace.entity.type","Publication"]]

[["dc.bibliographiccitation.firstpage","1907"],["dc.bibliographiccitation.issue","9"],["dc.bibliographiccitation.journal","Chemische Berichte"],["dc.bibliographiccitation.lastpage","1912"],["dc.bibliographiccitation.volume","124"],["dc.contributor.author","Meller, Anton"],["dc.contributor.author","Böker, Christian"],["dc.contributor.author","Seebold, Uwe"],["dc.contributor.author","Bromm, Dietmar"],["dc.contributor.author","Maringgele, Walter"],["dc.contributor.author","Heine, Andreas"],["dc.contributor.author","Herbst-Irmer, Regine"],["dc.contributor.author","Pohl, Ehmke"],["dc.contributor.author","Stalke, Dietmar"],["dc.contributor.author","Noltemeyer, Mathias"],["dc.contributor.author","Sheldrick, George M."],["dc.date.accessioned","2019-07-09T11:52:08Z"],["dc.date.available","2019-07-09T11:52:08Z"],["dc.date.issued","1991"],["dc.description.abstract","The reaction of subvalent boron species generated by the defluorination of difluoro(diorganylamino)borane with Na/K alloy in the presence of 1,4-disubstituted benzene derivatives leads to products which contain two (diorganylamino)boradiyl units and two remaining double bonds which are located on the substituted C atoms. Compounds 5 to 8 exhibit structures based on a 2,8-diborabicyclo[3,2,1]octa-3,6-diene skeleton while 9 shows a skeleton with a 1,3a,4,6a-tetrahydroborolo[3,2-b]borole structure. The latter structure corresponds to that of 1 obtained in the same reaction with benzene. The compounds are characterized by elemental analyses and spectroscopically [Mp. NMR (1H, 11B, 13C, 15N, 19F, 29Si)]. X-ray structure analyses are presented for 1, 6, 7, 8, and 9."],["dc.identifier.doi","10.1002/cber.19911240904"],["dc.identifier.purl","https://resolver.sub.uni-goettingen.de/purl?goescholar/3336"],["dc.identifier.uri","https://resolver.sub.uni-goettingen.de/purl?gro-2/60104"],["dc.language.iso","en"],["dc.notes.intern","Merged from goescholar"],["dc.rights","Goescholar"],["dc.rights.uri","https://goescholar.uni-goettingen.de/licenses"],["dc.subject.ddc","540"],["dc.title","Zweifache Borylierung von Benzolderivaten mit (Diisoalkylamino)boradiyl-Einheiten"],["dc.title.alternative","Twofold Borylation of Benzene Derivatives with (Diisoalkylamino)boradiyl Units"],["dc.type","journal_article"],["dc.type.internalPublication","yes"],["dc.type.version","published_version"],["dspace.entity.type","Publication"]]

[["dc.bibliographiccitation.firstpage","1927"],["dc.bibliographiccitation.issue","23"],["dc.bibliographiccitation.journal","Journal of the Chemical Society. Chemical communications"],["dc.bibliographiccitation.lastpage","1731"],["dc.contributor.author","Heine, Andreas"],["dc.contributor.author","Herbst-Irmer, Regine"],["dc.contributor.author","Stalke, Dietmar"],["dc.date.accessioned","2009-07-03T10:56:36Z"],["dc.date.accessioned","2021-10-27T13:12:03Z"],["dc.date.available","2009-07-03T10:56:36Z"],["dc.date.available","2021-10-27T13:12:03Z"],["dc.date.issued","1993"],["dc.description.abstract","The title compound is obtained from the reaction of (Me3Si)3SiLi(thf)3 with CuBr in n-hexane and structurally characterised by X-ray diffraction; in [Cu2R2BrLi(thf)3], R = Si(SiMe3)3 one silyl ligand is bridging a very short Cu–Cu bond, resulting in a three-centre two-electron bond, while the second is terminally bound to copper; the other copper atom is linked to a lithium atom via a Cu Br Li bridge."],["dc.format.mimetype","application/pdf"],["dc.identifier.doi","10.1039/C39930001729"],["dc.identifier.purl","https://resolver.sub.uni-goettingen.de/purl?goescholar/3391"],["dc.identifier.uri","https://resolver.sub.uni-goettingen.de/purl?gro-2/91654"],["dc.language.iso","en"],["dc.notes.intern","Migrated from goescholar"],["dc.relation.orgunit","Fakultät für Chemie"],["dc.rights","Goescholar"],["dc.rights.access","openAccess"],["dc.rights.uri","https://goescholar.uni-goettingen.de/licenses"],["dc.subject","anorganische Chemie"],["dc.subject.ddc","540"],["dc.title","[Cu2R2BrLi(thf)3], R = Si(SiMe3)3–a complex containing five-coordinate silicon in a three-centre two-electron bond (thf = tetrahydrofuran)"],["dc.type","journal_article"],["dc.type.internalPublication","yes"],["dc.type.peerReviewed","yes"],["dc.type.version","published_version"],["dspace.entity.type","Publication"]]

[["dc.bibliographiccitation.firstpage","1482"],["dc.bibliographiccitation.issue","8"],["dc.bibliographiccitation.journal","Acta Crystallographica / C"],["dc.bibliographiccitation.lastpage","1483"],["dc.bibliographiccitation.volume","49"],["dc.contributor.author","Besser, Susanne"],["dc.contributor.author","Herbst-Irmer, Regine"],["dc.contributor.author","Stalke, Dietmar"],["dc.contributor.author","Wright, Dominic S."],["dc.contributor.author","Snaith, Ronald"],["dc.contributor.author","Brooker, Alan T."],["dc.date.accessioned","2009-07-02T06:10:05Z"],["dc.date.accessioned","2021-10-27T13:12:06Z"],["dc.date.available","2009-07-02T06:10:05Z"],["dc.date.available","2021-10-27T13:12:06Z"],["dc.date.issued","1993"],["dc.description.abstract","The new sodium sulfide compound, #-hexasulfidolt~2S1,S 6:2n 2S1,S 6_bis{[N_(dimethylaminoethyl)_N,N,,_ N'-trimethyl- 1,2-ethanediamine-t~3N, N',N\"]sodium},[Na(pmdeta)]2[S6] (1) [pmdeta = (Me2NCH2CH2)2NMe],was obtained by reacting two equivalents of sodium hydride with elementary sulfur in toluene containing an excess of pmdeta at approximately 238 K. The crystal structure contains a central Na2p. ring in which both S atoms are part of an S~- residue. In addition, each Na atom is coordinated by a pmdeta molecule."],["dc.format.mimetype","application/pdf"],["dc.identifier.doi","10.1107/S0108270193001167"],["dc.identifier.purl","https://resolver.sub.uni-goettingen.de/purl?goescholar/3380"],["dc.identifier.uri","https://resolver.sub.uni-goettingen.de/purl?gro-2/91658"],["dc.language.iso","en"],["dc.notes.intern","Migrated from goescholar"],["dc.relation.orgunit","Fakultät für Chemie"],["dc.rights","Goescholar"],["dc.rights.access","openAccess"],["dc.rights.uri","https://goescholar.uni-goettingen.de/licenses"],["dc.subject","anorganische Chemie"],["dc.subject.ddc","540"],["dc.title","Structure of bis(pentamethyldiethylenetriamine)disodium hexasulfide"],["dc.type","journal_article"],["dc.type.internalPublication","yes"],["dc.type.peerReviewed","yes"],["dc.type.version","published_version"],["dspace.entity.type","Publication"]]