Molecular Solids as Ligands in Organometallic Chemistry: [CpTi6Na7F19·2.5thf] (Cp C5Me5) and [CpTi4Mg2F12·7thf], Links Between Ionic Solids and Organometallic Compounds

Date Issued
1994
Author(s)
Liu, Feng-Quan
Kuhn, Annja
DOI
10.1002/anie.199405551
Abstract
Central NaF and MgF2 frameworks are present in the title compounds obtained from the reaction of [Cp TiF3] (Cp C5Me5) with elemental sodium and magnesium, respectively. In these reactions TiIV is reduced to TiIII. The Cp Ti units function as organometallics shields around the cagelike core and are responsible for the high solubility of the compounds.
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