Sheldrick, George M.

[["dc.bibliographiccitation.firstpage","2339"],["dc.bibliographiccitation.journal","Dalton Transactions"],["dc.bibliographiccitation.lastpage","2341"],["dc.contributor.author","Bhaduri, Sumit"],["dc.contributor.author","Gopalkrishnan, Kalpathi S."],["dc.contributor.author","Sheldrick, George M."],["dc.contributor.author","Clegg, William"],["dc.contributor.author","Stalke, Dietmar"],["dc.date.accessioned","2009-06-10T11:46:14Z"],["dc.date.accessioned","2021-10-27T13:11:50Z"],["dc.date.available","2009-06-10T11:46:14Z"],["dc.date.available","2021-10-27T13:11:50Z"],["dc.date.issued","1983"],["dc.description.abstract","Triruthenium dodecacarbonyl [Ru3(CO)12] reacts with nitrobenzene to give [Ru3(CO)10(NPh)](3) and [Ru3(CO)9(NPh)2](4) in low yields, accompanied by formation of CO2. The solution i.r. spectrum of (3) suggests the presence of triply bridging NPh and CO groups, confirmed by a single-crystal X-ray structure determination; space group P21/n, a= 12.457(1), b= 11.428(1), c= 29.234(2)Å, = 92.38(1)°, Z= 8, and R= 0.036 for 4 817 unique observed reflections. The two independent molecules differ slightly in the relative orientations of the phenyl groups. Mean bond lengths include Ru–Ru 2.746(5), Ru–µ-C 2.172(8), and Ru–µ-N 2.055(5)Å. The i.r. Spectra of complexes (3) and (4) are discussed in terms of a molecular-orbital description of M3(CO)9 moieties."],["dc.format.mimetype","application/pdf"],["dc.identifier.doi","10.1039/DT9830002339"],["dc.identifier.purl","https://resolver.sub.uni-goettingen.de/purl?goescholar/3262"],["dc.identifier.uri","https://resolver.sub.uni-goettingen.de/purl?gro-2/91631"],["dc.language.iso","en"],["dc.notes.intern","Migrated from goescholar"],["dc.publisher","Chemical Society"],["dc.relation.orgunit","Fakultät für Chemie"],["dc.rights","Goescholar"],["dc.rights.access","openAccess"],["dc.rights.uri","https://goescholar.uni-goettingen.de/licenses"],["dc.subject","Anorganische Chemie"],["dc.subject.ddc","540"],["dc.title","Reaction of triruthenium dodecacarbonyl with nitrobenzene and structure of µ3-phenylnitrene-triruthenium decacarbonyl, [Ru3(CO)10(µ3-NPh)] : Notes. Reaction of triruthenium dodecacarbonyl with nitrobenzene and structure of µ3-phenylnitrene-triruthenium decacarbonyl, [Ru3(CO)10(µ3-NPh) : Notes"],["dc.type","journal_article"],["dc.type.internalPublication","yes"],["dc.type.peerReviewed","yes"],["dc.type.version","published_version"],["dspace.entity.type","Publication"]]

[["dc.bibliographiccitation.firstpage","1281"],["dc.bibliographiccitation.journal","Journal of Applied Crystallography"],["dc.bibliographiccitation.lastpage","1284"],["dc.bibliographiccitation.volume","44"],["dc.contributor.author","Huebschle, Christian Bertram"],["dc.contributor.author","Sheldrick, George M."],["dc.contributor.author","Dittrich, Birger"],["dc.date.accessioned","2018-11-07T08:49:18Z"],["dc.date.available","2018-11-07T08:49:18Z"],["dc.date.issued","2011"],["dc.description.abstract","ShelXle is a graphical user interface for SHELXL [Sheldrick, G. M. (2008). Acta Cryst. A64, 112-122], currently the most widely used program for small-molecule structure refinement. It combines an editor with syntax highlighting for the SHELXL-associated. ins (input) and. res (output) files with an interactive graphical display for visualization of a three-dimensional structure including the electron density (F-o) and difference density (F-o-F-c) maps. Special features of ShelXle include intuitive atom (re-)naming, a strongly coupled editor, structure visualization in various mono and stereo modes, and a novel way of displaying disorder extending over special positions. ShelXle is completely compatible with all features of SHELXL and is written entirely in C++ using the Qt4 and FFTW libraries. It is available at no cost for Windows, Linux and Mac-OS X and as source code."],["dc.identifier.doi","10.1107/S0021889811043202"],["dc.identifier.isi","000297279800022"],["dc.identifier.purl","https://resolver.sub.uni-goettingen.de/purl?gs-1/8692"],["dc.identifier.uri","https://resolver.sub.uni-goettingen.de/purl?gro-2/21427"],["dc.notes.intern","Merged from goescholar"],["dc.notes.status","zu prüfen"],["dc.notes.submitter","Najko"],["dc.publisher","Wiley-blackwell"],["dc.relation.issn","0021-8898"],["dc.rights","Goescholar"],["dc.rights.uri","https://goescholar.uni-goettingen.de/licenses"],["dc.title","ShelXle: a Qt graphical user interface for SHELXL"],["dc.type","journal_article"],["dc.type.internalPublication","yes"],["dc.type.peerReviewed","yes"],["dc.type.status","published"],["dc.type.version","published_version"],["dspace.entity.type","Publication"]]

[["dc.bibliographiccitation.firstpage","489"],["dc.bibliographiccitation.issue","3"],["dc.bibliographiccitation.journal","Chemische Berichte"],["dc.bibliographiccitation.lastpage","490"],["dc.bibliographiccitation.volume","123"],["dc.contributor.author","Maringgele, Walter"],["dc.contributor.author","Stalke, Dietmar"],["dc.contributor.author","Heine, Andreas"],["dc.contributor.author","Meller, Anton"],["dc.contributor.author","Sheldrick, George M."],["dc.date.accessioned","2019-07-09T11:52:03Z"],["dc.date.available","2019-07-09T11:52:03Z"],["dc.date.issued","1990"],["dc.description.abstract","The reaction of 1,3,5,7-cyclooctatetraene with sodium-postassium alloy and dihalogeno(diisopropylamino)boranes in 1,2-dimethoxyethane gives the title compound, characterized by elemental analysis, MS (EI, FI), NMR (1H, 11B, 13C), and X-ray crystallography."],["dc.identifier.doi","10.1002/cber.19901230314"],["dc.identifier.purl","https://resolver.sub.uni-goettingen.de/purl?goescholar/3298"],["dc.identifier.uri","https://resolver.sub.uni-goettingen.de/purl?gro-2/60080"],["dc.language.iso","en"],["dc.notes.intern","Merged from goescholar"],["dc.rights","Goescholar"],["dc.rights.uri","https://goescholar.uni-goettingen.de/licenses"],["dc.subject.ddc","540"],["dc.title","9-Diisopropylamino-9-borabicyclo[4.2.1]nona-2,4,7-triene from the Reaction of Cyclooctatetraene with Sodium-Potassium Alloy and Dihalogeno- (diisopropylamino)boranes"],["dc.type","journal_article"],["dc.type.internalPublication","yes"],["dc.type.version","published_version"],["dspace.entity.type","Publication"]]

[["dc.bibliographiccitation.firstpage","152"],["dc.bibliographiccitation.issue","4"],["dc.bibliographiccitation.journal","ChemistryOpen"],["dc.bibliographiccitation.lastpage","160"],["dc.bibliographiccitation.volume","3"],["dc.contributor.author","Kotyrba, Ursula M."],["dc.contributor.author","Proepper, Kevin"],["dc.contributor.author","Sachs, Eike-F."],["dc.contributor.author","Myanovska, Anastasiya"],["dc.contributor.author","Joppe, Tobias"],["dc.contributor.author","Lissy, Friederike"],["dc.contributor.author","Sheldrick, George M."],["dc.contributor.author","Koszinowski, Konrad"],["dc.contributor.author","Diederichsen, Ulf"],["dc.date.accessioned","2018-11-07T09:37:00Z"],["dc.date.available","2018-11-07T09:37:00Z"],["dc.date.issued","2014"],["dc.description.abstract","The DNA bisintercalator triostin A is structurally based on a disulfide-bridged depsipeptide scaffold that provides preorganization of two quinoxaline units in 10.5 angstrom distance. Triostin A analogues are synthesized with nucleobase recognition units replacing the quinoxalines and containing two additional recognition units in between. Thus, four nucleobase recognition units are organized on a rigid template, well suited for DNA double strand interactions. The new tetra-nucleobase binders are synthesized as aza-TANDEM derivatives lacking the N-methylation of triostin A and based on a cyclopeptide backbone. Synthesis of two tetra-nucleobase aza-TANDEM derivatives is established, DNA interaction analyzed by microscale thermophoresis, cytotoxic activity studied and a nucleobase sequence dependent self-aggregation investigated by mass spectrometry."],["dc.description.sponsorship","Deutsche Forschungsgemeinschaft [DI 542/7-1, SH 14/5-1]"],["dc.identifier.doi","10.1002/open.201400001"],["dc.identifier.isi","000341175700005"],["dc.identifier.pmid","25478311"],["dc.identifier.purl","https://resolver.sub.uni-goettingen.de/purl?gs-1/11914"],["dc.identifier.uri","https://resolver.sub.uni-goettingen.de/purl?gro-2/32739"],["dc.notes.intern","Merged from goescholar"],["dc.notes.status","zu prüfen"],["dc.notes.submitter","Najko"],["dc.publisher","Wiley-v C H Verlag Gmbh"],["dc.relation.issn","2191-1363"],["dc.rights","CC BY-NC 3.0"],["dc.rights.uri","https://creativecommons.org/licenses/by-nc/3.0"],["dc.title","Triostin A Derived Cyclopeptide as Architectural Template for the Alignment of Four Recognition Units"],["dc.type","journal_article"],["dc.type.internalPublication","yes"],["dc.type.peerReviewed","yes"],["dc.type.status","published"],["dc.type.version","published_version"],["dspace.entity.type","Publication"]]

[["dc.bibliographiccitation.firstpage","C15"],["dc.bibliographiccitation.journal","Journal of Organometallic Chemistry"],["dc.bibliographiccitation.lastpage","C19"],["dc.bibliographiccitation.volume","366"],["dc.contributor.author","Stalke, Dietmar"],["dc.contributor.author","Meyer, Matthias"],["dc.contributor.author","Andrianarison, Mbolatiana"],["dc.contributor.author","Klingebiel, Uwe"],["dc.contributor.author","Sheldrick, George M."],["dc.date.accessioned","2009-06-23T12:09:38Z"],["dc.date.accessioned","2021-10-27T13:11:51Z"],["dc.date.available","2009-06-23T12:09:38Z"],["dc.date.available","2021-10-27T13:11:51Z"],["dc.date.issued","1989"],["dc.description.abstract","Di-t-butylfluorosilylphenylphosphane (I) reacts with CMe3Li to give the lithium compound [(CMe3)2SiFLi(THF)2PC6H5]2 (II) and butane. The crystal structure of II has been determined. The Si---P bond length (217.1 pm) in the eight-membered ring is extremely short. The Si---P spin coupling constant (84.12 Hz) in II is remarkably large. LiF elimination from II leads to the formation of the four-membered (Si---P) ring III. The bis(fluorosilyl)phosphane IV is formed in the reaction of II with Me2SiF2."],["dc.format.mimetype","application/pdf"],["dc.identifier.doi","10.1016/0022-328X(89)87193-1"],["dc.identifier.purl","https://resolver.sub.uni-goettingen.de/purl?goescholar/3286"],["dc.identifier.uri","https://resolver.sub.uni-goettingen.de/purl?gro-2/91632"],["dc.language.iso","de"],["dc.notes.intern","Migrated from goescholar"],["dc.relation.orgunit","Fakultät für Chemie"],["dc.rights","Goescholar"],["dc.rights.access","openAccess"],["dc.rights.uri","https://goescholar.uni-goettingen.de/licenses"],["dc.subject","anorganische Chemie"],["dc.subject.ddc","540"],["dc.title","Lithio-di-t-butylfluorsilylphenylphosphan; im Kristall ein (SiFLiP)2-Achtring"],["dc.type","journal_article"],["dc.type.internalPublication","yes"],["dc.type.peerReviewed","yes"],["dc.type.version","published_version"],["dspace.entity.type","Publication"]]

[["dc.bibliographiccitation.firstpage","779"],["dc.bibliographiccitation.issue","4"],["dc.bibliographiccitation.journal","Chemische Berichte"],["dc.bibliographiccitation.lastpage","782"],["dc.bibliographiccitation.volume","123"],["dc.contributor.author","Dippel, Kerstin"],["dc.contributor.author","Klingebiel, Uwe"],["dc.contributor.author","Pauer, Frank"],["dc.contributor.author","Sheldrick, George M."],["dc.contributor.author","Stalke, Dietmar"],["dc.date.accessioned","2019-07-09T11:52:03Z"],["dc.date.available","2019-07-09T11:52:03Z"],["dc.date.issued","1990"],["dc.description.abstract","Ring Contractions of Octamethylcyclotetrasilazanes to Silyl-Substituted Cyclotrisilazanes Reaction of the mono- and dilithium derivatives of bis(fluorsilyl)-substituted cyclotetrasilazanes with fluorosilanes and fluoroboranes leads to ring contraction with formation of cyclotrisilazanes (1 - 8). The isomerisation is proved by the crystal structure determination of 1 and by NMR spectroscopy."],["dc.identifier.doi","10.1002/cber.19901230421"],["dc.identifier.purl","https://resolver.sub.uni-goettingen.de/purl?goescholar/3299"],["dc.identifier.uri","https://resolver.sub.uni-goettingen.de/purl?gro-2/60081"],["dc.language.iso","en"],["dc.notes.intern","Merged from goescholar"],["dc.rights","Goescholar"],["dc.rights.uri","https://goescholar.uni-goettingen.de/licenses"],["dc.subject.ddc","540"],["dc.title","Ringkontraktionsreaktionen von Octamethylcyclotetrasilazanen zu silylsubstituierten Cyclotrisilazanen"],["dc.type","journal_article"],["dc.type.internalPublication","yes"],["dc.type.version","published_version"],["dspace.entity.type","Publication"]]

[["dc.bibliographiccitation.firstpage","1828"],["dc.bibliographiccitation.issue","12"],["dc.bibliographiccitation.journal","Angewandte Chemie"],["dc.bibliographiccitation.lastpage","1830"],["dc.bibliographiccitation.volume","105"],["dc.contributor.author","Schulz, Stephan"],["dc.contributor.author","Roesky, Herbert W."],["dc.contributor.author","Koch, Hans-Joachim"],["dc.contributor.author","Sheldrick, George M."],["dc.contributor.author","Stalke, Dietmar"],["dc.contributor.author","Kuhn, Annja"],["dc.date.accessioned","2019-07-09T11:52:15Z"],["dc.date.available","2019-07-09T11:52:15Z"],["dc.date.issued","1993"],["dc.identifier.doi","10.1002/ange.19931051233"],["dc.identifier.purl","https://resolver.sub.uni-goettingen.de/purl?goescholar/3395"],["dc.identifier.uri","https://resolver.sub.uni-goettingen.de/purl?gro-2/60134"],["dc.language.iso","de"],["dc.notes.intern","Merged from goescholar"],["dc.rights","Goescholar"],["dc.rights.uri","https://goescholar.uni-goettingen.de/licenses"],["dc.subject.ddc","540"],["dc.title","Eine einfache Synthese von [(Cp Al)4] und dessen Umsetzung zu den Heterocubanen [(Cp AlSe)4] und [(Cp AlTe)4] (Cp = 5-C5(CH3)5)"],["dc.type","journal_article"],["dc.type.internalPublication","yes"],["dc.type.version","published_version"],["dspace.entity.type","Publication"]]

[["dc.bibliographiccitation.firstpage","2694"],["dc.bibliographiccitation.issue","12"],["dc.bibliographiccitation.journal","Inorganic Chemistry"],["dc.bibliographiccitation.lastpage","2698"],["dc.bibliographiccitation.volume","32"],["dc.contributor.author","Heine, Andreas"],["dc.contributor.author","Herbst-Irmer, Regine"],["dc.contributor.author","Sheldrick, George M."],["dc.contributor.author","Stalke, Dietmar"],["dc.date.accessioned","2019-07-09T11:52:13Z"],["dc.date.available","2019-07-09T11:52:13Z"],["dc.date.issued","1993"],["dc.description.abstract","The crystal structures of (MesSi),Si.THF (a = b = 12.310(1) A, c = 17.308(2) A, tetragonal, space group P4/ncc (No. 130), Z = 4), [(Me3Si)&i][(Me3Si)3SiLi(THF)3](a~ = b = 15.146(8) A, c = 21.338(10) A, trigonal, space groupP3cl (No. 165), Z = 2), (Me3Si)3SiLi(THF)3 (a = b = 31.342(4) A, c = 22.000(6) A, rhombohedral, space groupR3c (No. 161), Z = 24), and (Me3Si)3SiSi(SiMe3)3aTHF (a = 11.360(3) A, b = 17.131(6) A, c = 18.952(6) A, 0 = 91.21(3)', monoclinic, space group P21/c (No. 14), Z = 4), have been determined by low-temperature X-ray analysis. Whereas the small S i S i S i angle in (tris(trimethylsily1)silyl)lithium of 102.1 O supports the ionic character of the Si-Li bond, there must be at least some covalent contribution leading to a J[%,7Li] coupling constant of 38.6 Hz. A modified preparation for (Me3si)~siLi(THF)is~ reported giving the pure product rather than the cocrystallization product [(Me3Si)4Si] [(Me3Si)3SiLi(THF)3]2, where the starting material is still present in the ratio 1:2. The pure product is far more reactive than the cocrystallized material and is as pyrophoric as 'BuLi powder."],["dc.identifier.doi","10.1021/ic00064a019"],["dc.identifier.purl","https://resolver.sub.uni-goettingen.de/purl?goescholar/3369"],["dc.identifier.uri","https://resolver.sub.uni-goettingen.de/purl?gro-2/60120"],["dc.language.iso","en"],["dc.notes.intern","Merged from goescholar"],["dc.rights","Goescholar"],["dc.rights.uri","https://goescholar.uni-goettingen.de/licenses"],["dc.subject.ddc","540"],["dc.title","Structural characterization of two modifications of tris(tetrahydrofuran)(tris(trimethylsilyl)silyl)lithium: a compound with a silicon-29-lithium-7 NMR coupling"],["dc.type","journal_article"],["dc.type.internalPublication","yes"],["dc.type.version","published_version"],["dspace.entity.type","Publication"]]

[["dc.bibliographiccitation.firstpage","33"],["dc.bibliographiccitation.journal","Journal of Organometallic Chemistry"],["dc.bibliographiccitation.lastpage","39"],["dc.bibliographiccitation.volume","452"],["dc.contributor.author","Oehme, Hartmut"],["dc.contributor.author","Wustrack, R."],["dc.contributor.author","Heine, Andreas"],["dc.contributor.author","Sheldrick, George M."],["dc.contributor.author","Stalke, Dietmar"],["dc.date.accessioned","2009-07-01T10:42:28Z"],["dc.date.accessioned","2021-10-27T13:12:34Z"],["dc.date.available","2009-07-01T10:42:28Z"],["dc.date.available","2021-10-27T13:12:34Z"],["dc.date.issued","1993"],["dc.description.abstract","Das Reaktionsverhalten von (Me3Si)3SiLi (1) mit Aceton wurde durch die Strukturanalyse und 29Si-NMR-Untersuchungen von H(Me3Si)2Si---(Me3Si)2Si---CMe2SiMe3 (3) und (Me3Si)3Si---(Me3Si)2Si---CMe2SiMe3 (4) aufgeklärt. Die zwar chemisch aber nicht kristallographisch äquivalenten Siliciumatome in 3 und 4 und die zwei kristallographisch unabhängigen Moleküle in 4 lassen sich alle im 29Si-MAS-CP-Spektrum auflösen. Die 1J(29Si, 29Si)-Kopplungen in Lösung erleichtern dabei das Zuordnen der 29Si-Resonanzen. Abstract: The reaction of (Me3Si)3SiLi (1) with acetone has been clarified with the aid of crystal structure and 29p. NMR investigations of H(Me3Si)2Si---(Me3Si)2Si---CMe2SiMe3 (3) and (Me3Si)3Si---(Me3Si)2Si---CMe2SiMe3 (4). The chemically but not crystallographically equivalent silicon atoms in 3 and 4 and the two crystallographically independent molecules of 4 all gave rise to separate signals in the solid state 29Si-MAS NMR spectra. The 1J(29Si, 29Si) couplings observed in solution facilitated the assignment of 29Si resonances."],["dc.format.mimetype","application/pdf"],["dc.identifier.doi","10.1016/0022-328X(93)83169-V"],["dc.identifier.purl","https://resolver.sub.uni-goettingen.de/purl?goescholar/3375"],["dc.identifier.uri","https://resolver.sub.uni-goettingen.de/purl?gro-2/91703"],["dc.language.iso","de"],["dc.notes.intern","Migrated from goescholar"],["dc.relation.orgunit","Fakultät für Chemie"],["dc.rights","Goescholar"],["dc.rights.access","openAccess"],["dc.rights.uri","https://goescholar.uni-goettingen.de/licenses"],["dc.subject","anorganische Chemie"],["dc.subject.ddc","540"],["dc.title","Strukturuntersuchungen an den Produkten aus der Reaktion des Tris(trimethylsilyl)silyllithiums mit Aceton"],["dc.type","journal_article"],["dc.type.internalPublication","yes"],["dc.type.peerReviewed","yes"],["dc.type.version","published_version"],["dspace.entity.type","Publication"]]

[["dc.bibliographiccitation.firstpage","1321"],["dc.bibliographiccitation.journal","Acta Crystallographica Section D Biological Crystallography"],["dc.bibliographiccitation.lastpage","1335"],["dc.bibliographiccitation.volume","70"],["dc.contributor.author","Sidhu, Navdeep S."],["dc.contributor.author","Schreiber, Kathrin"],["dc.contributor.author","Proepper, Kevin"],["dc.contributor.author","Becker, Stefan"],["dc.contributor.author","Uson, Isabel"],["dc.contributor.author","Sheldrick, George M."],["dc.contributor.author","Gärtner, Jutta"],["dc.contributor.author","Kraetzner, Ralph"],["dc.contributor.author","Steinfeld, Robert"],["dc.date.accessioned","2017-09-07T11:46:15Z"],["dc.date.available","2017-09-07T11:46:15Z"],["dc.date.issued","2014"],["dc.description.abstract","Mucopolysaccharidosis type IIIA (Sanfilippo A syndrome), a fatal childhood-onset neurodegenerative disease with mild facial, visceral and skeletal abnormalities, is caused by an inherited deficiency of the enzyme N-sulfoglucosamine sulfohydrolase (SGSH; sulfamidase). More than 100 mutations in the SGSH gene have been found to reduce or eliminate its enzymatic activity. However, the molecular understanding of the effect of these mutations has been confined by a lack of structural data for this enzyme. Here, the crystal structure of glycosylated SGSH is presented at 2 A resolution. Despite the low sequence identity between this unique N-sulfatase and the group of O-sulfatases, they share a similar overall fold and active-site architecture, including a catalytic formylglycine, a divalent metal-binding site and a sulfate-binding site. However, a highly conserved lysine in O-sulfatases is replaced in SGSH by an arginine (Arg282) that is positioned to bind the N-linked sulfate substrate. The structure also provides insight into the diverse effects of pathogenic mutations on SGSH function in mucopolysaccharidosis type IIIA and convincing evidence for the molecular consequences of many missense mutations. Further, the molecular characterization of SGSH mutations will lay the groundwork for the development of structure-based drug design for this devastating neurodegenerative disorder."],["dc.identifier.doi","10.1107/S1399004714002739"],["dc.identifier.gro","3142131"],["dc.identifier.isi","000335952500014"],["dc.identifier.pmid","24816101"],["dc.identifier.purl","https://resolver.sub.uni-goettingen.de/purl?gs-1/12116"],["dc.identifier.uri","https://resolver.sub.uni-goettingen.de/purl?gro-2/4888"],["dc.notes.intern","WoS Import 2017-03-10"],["dc.notes.intern","Merged from goescholar"],["dc.notes.status","final"],["dc.notes.submitter","PUB_WoS_Import"],["dc.publisher","Wiley-blackwell"],["dc.relation.issn","1399-0047"],["dc.rights","Goescholar"],["dc.rights.uri","https://goescholar.uni-goettingen.de/licenses"],["dc.title","Structure of sulfamidase provides insight into the molecular pathology of mucopolysaccharidosis IIIA"],["dc.type","journal_article"],["dc.type.internalPublication","yes"],["dc.type.peerReviewed","yes"],["dc.type.subtype","original"],["dc.type.version","published_version"],["dspace.entity.type","Publication"]]