Karius, Volker

[["dc.bibliographiccitation.firstpage","3509"],["dc.bibliographiccitation.issue","16"],["dc.bibliographiccitation.journal","Chemistry – A European Journal"],["dc.bibliographiccitation.lastpage","3514"],["dc.bibliographiccitation.volume","26"],["dc.contributor.author","Choi, Isaac"],["dc.contributor.author","Müller, Valentin"],["dc.contributor.author","Lole, Gaurav"],["dc.contributor.author","Köhler, Robert"],["dc.contributor.author","Karius, Volker"],["dc.contributor.author","Viöl, Wolfgang"],["dc.contributor.author","Jooss, Christian"],["dc.contributor.author","Ackermann, Lutz"],["dc.date.accessioned","2021-04-14T08:27:16Z"],["dc.date.available","2021-04-14T08:27:16Z"],["dc.date.issued","2020"],["dc.description.abstract","Abstract Heterogeneous copper catalysis enabled photoinduced C−H arylations under exceedingly mild conditions at room temperature. The versatile hybrid copper catalyst provided step‐economical access to arylated heteroarenes, terpenes and alkaloid natural products with various aryl halides. The hybrid copper catalyst could be reused without significant loss of catalytic efficacy. Detailed studies in terms of TEM, HRTEM and XPS analysis of the hybrid copper catalyst, among others, supported its outstanding stability and reusability."],["dc.description.abstract","Let there be light: C−H arylations were realized at room temperature with a hybrid copper catalyst, enabling catalyst recycling and reuse. image"],["dc.description.sponsorship","Deutsche Forschungsgemeinschaft http://dx.doi.org/10.13039/501100001659"],["dc.description.sponsorship","Kwanjeong Educational Foundation http://dx.doi.org/10.13039/501100004093"],["dc.identifier.doi","10.1002/chem.202000192"],["dc.identifier.eissn","1521-3765"],["dc.identifier.issn","0947-6539"],["dc.identifier.uri","https://resolver.sub.uni-goettingen.de/purl?gro-2/82222"],["dc.language.iso","en"],["dc.notes.intern","DOI Import GROB-399"],["dc.relation","SFB 1073: Kontrolle von Energiewandlung auf atomaren Skalen"],["dc.relation","SFB 1073 | Topical Area C | C02 In situ hochauflösende Untersuchung des aktiven Zustands bei der photo- und elektrochemischen Wasserspaltung"],["dc.relation.eissn","1521-3765"],["dc.relation.issn","0947-6539"],["dc.relation.orgunit","Institut für Materialphysik"],["dc.rights","This is an open access article under the terms of the Creative Commons Attribution License, which permits use, distribution and reproduction in any medium, provided the original work is properly cited."],["dc.title","Photoinduced Heterogeneous C−H Arylation by a Reusable Hybrid Copper Catalyst"],["dc.type","journal_article"],["dc.type.internalPublication","yes"],["dc.type.subtype","original_ja"],["dspace.entity.type","Publication"]]

[["dc.bibliographiccitation.firstpage","15290"],["dc.bibliographiccitation.issue","66"],["dc.bibliographiccitation.journal","Chemistry – A European Journal"],["dc.bibliographiccitation.lastpage","15297"],["dc.bibliographiccitation.volume","26"],["dc.contributor.author","Choi, Isaac"],["dc.contributor.author","Müller, Valentin"],["dc.contributor.author","Wang, Yanhui"],["dc.contributor.author","Xue, Kai"],["dc.contributor.author","Kuniyil, Rositha"],["dc.contributor.author","Andreas, Loren B."],["dc.contributor.author","Karius, Volker"],["dc.contributor.author","Alauzun, Johan G."],["dc.contributor.author","Ackermann, Lutz"],["dc.date.accessioned","2021-04-14T08:32:22Z"],["dc.date.available","2021-04-14T08:32:22Z"],["dc.date.issued","2020"],["dc.description.abstract","Abstract We disclose the unprecedented hybrid‐ruthenium catalysis for distal meta‐C−H activation. The hybrid‐ruthenium catalyst was recyclable, as was proven by various heterogeneity tests, and fully characterized with various microscopic and spectroscopic techniques, highlighting the physical and chemical stability. Thereby, the hybrid‐ruthenium catalysis proved broadly applicable for meta‐C−H alkylations of among others purine‐based nucleosides and natural product conjugates. Additionally, its versatility was further reflected by meta‐C−H activations through visible‐light irradiation, as well as para‐selective C−H activations."],["dc.description.abstract","Don't say goodbye! Recyclable ruthenium catalyst enabled diverse distal C−H functionalization. State‐of‐the‐art spectroscopic and spectrometric characterizations highlighted physical and chemical stability of reusable hybrid‐ruthenium catalyst. Robustness and versatility of hybrid‐ruthenium catalysis was further reflected by meta‐ and para‐selectivity as well as visible‐light‐induced reactivity. image"],["dc.description.sponsorship","Horizon 2020 Framework Programme http://dx.doi.org/10.13039/100010661"],["dc.description.sponsorship","Kwanjeong Educational Foundation http://dx.doi.org/10.13039/501100004093"],["dc.description.sponsorship","DFG http://dx.doi.org/10.13039/501100001659"],["dc.description.sponsorship","Max Planck Institute for Biophysical Chemistry"],["dc.identifier.doi","10.1002/chem.202003622"],["dc.identifier.uri","https://resolver.sub.uni-goettingen.de/purl?gro-2/83894"],["dc.language.iso","en"],["dc.notes.intern","DOI Import GROB-399"],["dc.relation.eissn","1521-3765"],["dc.relation.issn","0947-6539"],["dc.rights","This is an open access article under the terms of the Creative Commons Attribution‐NonCommercial License, which permits use, distribution and reproduction in any medium, provided the original work is properly cited and is not used for commercial purposes."],["dc.title","Recyclable Ruthenium Catalyst for Distal meta ‐C−H Activation"],["dc.type","journal_article"],["dc.type.internalPublication","yes"],["dspace.entity.type","Publication"]]