Acetylacetonatodifluorooxometalates of vanadium and molybdenum: syntheses and crystal structures

ISSN
1472-7773
Date Issued
2001
Author(s)
Schormann, M.
Prust, J.
Schmidt, H. G.
Noltemeyer, M.
DOI
10.1039/b100740h
Abstract
[Et4N][HF2] reacted with VO(acac)(2) and MoO2(acac)(2) in acetonitrile at room temperature with elimination of Hacac to produce the metalates [Et4N][(acac)VOF2] 1 and [Et4N][(acac)MoO2F2] 2, respectively. These compounds are the first examples of fluorometalates of vanadium and molybdenum bearing the acetylacetonato group. The crystal structures have been determined.